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Confirmatory tests for anions

Qualitative Inorganic Analysis · Chemistry

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A salt gives white ppt with BaCl₂, insoluble in HCl. Identify the anion. Step 1: Ba²⁺ precipitates CO₃²⁻, SO₃²⁻, SO₄²⁻ as white salts. Step 2: BaCO₃ and BaSO₃ dissolve in HCl; BaSO₄ doesn't. Step 3: Insoluble in HCl → SO₄²⁻. Step 4: Confirm: the test is specific — sulphate confirmed!

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